Use of phase-transfer reaction conditions for the hydrogenation of conjugated dienes and. alpha.,. beta.-unsaturated ketones with a homogeneous metal hydride …
DL Reger, MM Habib, DJ Fauth
文献索引：Reger, Daniel L.; Habib, M. M.; Fauth, D. J. Journal of Organic Chemistry, 1980 , vol. 45, # 19 p. 3860 - 3865
The homogeneous water-soluble hydrogenation catalyst K,[CO (CN)~ H] has been shown to be very active in hydrogenation reactions with conjugated dienes and a, P-unsaturated ketones when used under phase-transfer reaction conditions. Thus, conjugated dienes are converted into monoenes, generally with overall 1, 4-addition to yield E products, and a, p- unsaturated ketones to saturated ketones in high yield. Because of rate accelerations, ...
