Tetrahedron

… with alkaline hydrogen peroxide as a convenient route for the cis-hydration of alkenes via hydroboration11For part 1 in this series, see: HC Brown and KJ Murray, …

HC Brown, C Snyder, BCS Rao, G Zweifel

文献索引：Brown, Herbert C.; Snyder, Carl; Rao, B. C. Subba; Zweifel, George Tetrahedron, 1986 , vol. 42, # 20 p. 5505 - 5510

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被引用次数: 31

摘要

Aqueous hydrogen peroxide in the presence of dilute alkali effects the oxidation of organoboranes. The conditions necessary for a clean and quantitative transformation of organoboranes into the corresponding alcohols have been established. Thus, one mole of trialkylborane reacts with three moles of hydrogen peroxide in the presence of one mole of sodium hydroxide to provide three moles of the corresponding alcohol. The ...