Journal of fluorine chemistry

Electrophilic reactions of trihalogenomethanesulfenyl acetates and trifluoroacetates

A Haas, M Lieb, Y Zhang

文献索引：Haas,A.; Lieb,M.; Zhang,Y. Journal of Fluorine Chemistry, 1985 , vol. 29, p. 297

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被引用次数: 17

摘要

Abstract The stable trihalogenomethanesulfenyl acetates, AcOSCF n Cl 3− n (2) were prepared by the reaction of the corresponding trihalogeno-methanesulfenyl chlorides with sodium acetate. These and fluoro-chloromethanesulfenyl trifluoracetates CF 3 COOSCF n Cl 3− n (1) added rapidly in trans manner to cyclohexene to yield β-acetoxy and β- trifluoroacetoxy sulfides (3). The trifluoroacetates (1) also reacted with some aromatics ...