The preparation of thiazyltrifluoromethane, CF3SN, the hexachloro-3-cyclopentenylidenaminosulfides C5Cl6NSX (X= CF3, Cl, NSO, SCF3, C5Cl6N) and the crystal …
T Mischo
文献索引:Haas, Alois; Mischo, Thomas Canadian Journal of Chemistry, 1989 , vol. 67, p. 1902 - 1908
CF3S (Cl)= NSi (CH3) 3 is found to undergo intermolecular decomposition to give oligomeric, possibly cyclic (CF3SN) x rather than monomeric CF3SN, formed by intramolecular decomposition. Monomeric thiazyltrifluoromethane, CF3SN, is formed in the