RSC Advances

Magnetically recoverable catalytic Co–Co 2 B nanocomposites for the chemoselective reduction of aromatic nitro compounds

AA Vernekar, S Patil, C Bhat, SG Tilve

文献索引：Vernekar, Amit A.; Patil, Sagar; Bhat, Chinmay; Tilve, Santosh G. RSC Advances, 2013 , vol. 3, # 32 p. 13243 - 13250

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被引用次数: 12

摘要

Magnetically recoverable and recyclable Co–Co2B nanocomposites are described for the catalytic and chemoselective reduction of nitroarenes using two different hydrogen sources, sodium borohydride and hydrazine hydrate. Both the systems display an interesting chemoselective reduction switch. The kinetics of reduction of nitroaromatics were studied for the first time and follow nitroreductase enzyme-like kinetics with exceedingly high Kcat ( ...