Generation of an Aromatic Amide??Derived Phosphane (Aphos) Library by Self??Assisted Molecular Editing and Applications of Aphos in Room??Temperature Suzuki– …

…, Y Li, Y Zhang, C Yue, J Wu

文献索引：Dai, Wei-Min; Li, Yannian; Zhang, Ye; Yue, Congyong; Wu, Jinlong Chemistry - A European Journal, 2008 , vol. 14, # 18 p. 5538 - 5554

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被引用次数: 42

摘要

Abstract Aromatic amide-derived phosphanes (Aphos) are hemilabile P, O-coordinating ligands, which, when combined with a Pd precursor, yield a promising precatalyst system for Suzuki–Miyaura cross-coupling reactions. A focused library of Aphos ligands has been constructed for structural optimization, with the target of improving catalytic efficacy. By using microwave irradiation at accurately regulated temperature, an expeditious and ...