Journal of the Chemical Society, Perkin Transactions 1

Nucleophilic fluorination of alkoxysilane with alkali metal salts of perfluorinated complex anions. 1a Part 21b

O Farooq

文献索引：Farooq, Omar Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 4 p. 661 - 665

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被引用次数: 16

摘要

Alkali metal salts of perfluorinated complex anions have been used to effect nucleophilic fluorination of alkyl-, arylalkyl-and arylalkoxy-silanes both in the presence and absence of solvent. Near-quantitative yields of fluorinated silanes are obtained using equimolar quantities of fluoride ion equivalents and alkoxysilanes. In certain cases, intermediate organoboron and organophosphorus compounds derived from the corresponding ...