Organic letters

Enzymatic dynamic kinetic resolution of (±)-cis-N-(alkoxycarbonyl) cyclopentane-1, 2-diamines based on spontaneous racemization

FJ Quijada, V Gotor, F Rebolledo

文献索引：Organic Letters, , vol. 12, # 16 p. 3602 - 3605

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被引用次数: 14

摘要

... Volume: Page: ... Organic Letters. ... CAL-B,(11) first using ethyl acetate as acyl donor and solvent (Scheme 1, entry 1). Under these conditions, the enzyme catalyzed the acetylation of the amino group of 5a, though with moderate enantioselectivity (E = 48).(12) In an ...