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The Journal of Organic Chemistry

Synthetic routes to 6, 8-dioxabicyclo [3.2. 1] octyl pheromones from D-glucose derivatives. 2. Synthesis of (+)-exo-brevicomin

AE Sherk, B Fraser-Reid

文献索引:Sherk, Alfred E.; Fraser-Reid, Bert Journal of Organic Chemistry, 1982 , vol. 47, # 6 p. 932 - 935

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被引用次数: 27

摘要

2 3 1 first of these, exo-brevicomin (I), was isolated only in 1969 by Silverstein.'Subsequently , frontalin (2) s and multistriatin (3) s were added. We have studied the preparation of all three from derivatives of D-glucose and now report our results, some of which have appeared in preliminary form. lOJ1 In this paper we describe our work on exo-brevicomin (l), and in the accompanying papers we discuss frontalin (2) 12 and a-multistriatin (3). 13