Synthesis

BODP-A Versatile Reagent for Phospholipid Synthesis

PL Zaffalon, A Zumbuehl

文献索引：Zaffalon, Pierre-Leonard; Zumbuehl, Andreas Synthesis, 2011 , # 5 p. 778 - 782

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被引用次数: 5

摘要

On attempting to phosphorylate a secondary alcohol, we found that phosphorus(V) reagents are generally too unreactive and phosphorus(III) reagents lead to oxidation after the addition of the first alcohol. This and the cost of phosphoramidite reagents led us to look for an alternative, a middle way using a reagent that at the same time was stable towards oxidation, but also reactive enough to allow the stepwise addition of two different alcohols ...