Tetrahedron

Oxymetallation. Part 24. Preparation of cyclic peroxides by cycloperoxymercuriation of unsaturated hydroperoxides.

AJ Bloodworth, RJ Curtis, MD Spencer, NA Tallant

文献索引：Bloodworth; Curtis; Spencer; Tallant Tetrahedron, 1993 , vol. 49, # 13 p. 2729 - 2750

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被引用次数: 35

摘要

Seventeen unsaturated hydroperoxides have been converted by treatment with mercury (II) acetate and/or mercury (II) nitrate into nineteen new mercuriated cyclic peroxides and by subsequent demercuriation with alkaline sodium borohydride, six new mercury-free peroxides have been isolated. The results greatly extend the range of such reactions and provide information about the stereoselectivities and relative ease of several different ...