A general model for selectivity in olefin cross metathesis

AK Chatterjee, TL Choi, DP Sanders…

文献索引：Chatterjee, Arnab K.; Choi, Tae-Lim; Sanders, Daniel P.; Grubbs, Robert H. Journal of the American Chemical Society, 2003 , vol. 125, # 37 p. 11360 - 11370

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被引用次数: 1192

摘要

In recent years, olefin cross metathesis (CM) has emerged as a powerful and convenient synthetic technique in organic chemistry; however, as a general synthetic method, CM has been limited by the lack of predictability in product selectivity and stereoselectivity. Investigations into olefin cross metathesis with several classes of olefins, including substituted and functionalized styrenes, secondary allylic alcohols, tertiary allylic alcohols, ...