Applied Organometallic Chemistry

Accelerated Heck reaction using ortho??palladated complex in a nonaqueous ionic liquid with controlled microwave heating

AR Hajipour, F Rafiee

文献索引：Hajipour, Abdol R.; Rafiee, Fatemeh Applied Organometallic Chemistry, 2011 , vol. 25, # 7 p. 542 - 551

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被引用次数: 27

摘要

Abstract The activity of {Pd [C 6 H 2 (CH 2 CH 2 NH 2)-(OMe) 2, 3, 4](µ-Br)} 2 complex was investigated in the Heck–Mizoroki C [BOND] C cross-coupling reaction under conventional heating and microwave irradiation conditions in molten salt tetrabutylammonium bromide as the solvent and promoter at 130 C. This complex in these conditions is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides, and also ...