Journal of Organometallic Chemistry

Studies of the use of elemento-organic compounds of the fifteenth and sixteenth groups in organic synthesis LXXI. Reaction of α-halogeno carboxylic derivatives with …

YZ Huang, C Chen, Y Shen

文献索引：Huang, Yao-Zeng; Chen, Chen; Shen, Yanchang Journal of Organometallic Chemistry, 1989 , vol. 366, p. 87 - 94

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被引用次数: 0

摘要

Abstract α, β-Unsaturated esters and amides were conveniently obtained from the trialkylstibine-promoted reaction of α-halogenocarboxylic derivatives with carbonyl compounds. In this reaction, a quaternary stibonium salt is an active intermediate that can be trapped and can undergo further reaction with the substrate.