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Benzotropyl+ benzene. dha. tropyl+ naphthalene

M Pomerantz, AS Ross

文献索引:Pomerantz,M.; Ross,A.S. Journal of the American Chemical Society, 1975 , vol. 97, # 20 p. 5850 - 5855

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被引用次数: 4

摘要

Abstract: Pyrolysis (400') of 1, 2-benzotropiIidene (1) has been shown to produce naphthalene (Z), 2-methylnaphthalene (3), 1-methylnaphthalene (g), benzocycloheptene (5), and benzocycloheptadiene (6). The formation of naphthalene was shown not to involve extrusion of methylene, even though in the presence of benzene toluene was produced, but did involve free radicals. Initiation by di-tert-butyl nitroxide at 300'produced naphthalene ...