Inorganic Chemistry

Magnetodynamic effects on outer-sphere electron-transfer reactions: a paramagnetic transition state

S Ronco, G Ferraudi

文献索引：Ronco, S.; Ferraudi, G. Inorganic Chemistry, 1990 , vol. 29, p. 3961 - 3967

被引用次数: 19

摘要

The effect of the magnetic field on the rate of outer-sphere electron-transfer reactions has been investigated as a function of the field intensity, between 0 and 9 T, and at a given temperature. In complexes of d6 metal ions, Le., Ru (I1) and Co (III), the rate constant exhibits a complex dependence on the field: a complexity associated with field-induced changes of the electronic matrix element and the activation energy. Changes in the ...

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