Electron-transfer reactivity in some simple cobalt (III)-cobalt (II) couples. Franck-Condon vs. electronic contributions

…, T Ramasami, K Kumar, K Dwarakanath…

文献索引：Endicott, John F.; Brubaker, George R.; Ramasami, T.; Kumar, Krishan; Dwarakanath, Kaddi; et al. Inorganic Chemistry, 1983 , vol. 22, p. 3754 - 3762

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被引用次数: 51

摘要

Electron-transfer rates involving the C~(sep)~+*~+(sep= 1, 3, 6, 8, 10, 13, 16, 19- octaazabicyclo [6.6. 6] eicosane) and C~(en)~~+,~+ couples have been examined for any differences in contributions of Franck-Condon and electronic terms to the rate constants. Rate constants for cross-reaction oxidations of Co (sep)*+ follow the classically predicted dependence of the Franck-Condon factor on AGab0. Far-infrared and Raman vibrational ...