Electrolytic partial fluorination of organic compounds. 12. Selective anodic monofluorination of fluoroalkyl and alkyl sulfides

T Fuchigami, A Konno, K Nakagawa…

文献索引：Fuchigami, Toshio; Konno, Akinori; Nakagawa, Kiyono; Shimojo, Moriyasu Journal of Organic Chemistry, 1994 , vol. 59, # 20 p. 5937 - 5941

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被引用次数: 64

摘要

Highly regioselective anodic monofluorination of various aryl and alkyl fluoroalkyl sulfides was successfully carried out, and fluorine was exclusively (aryl sulfides) or preferentially (alkyl sulfides) introduced at the position a to the fluoroalkyl group. Even simple alkyl phenyl sulfides devoid of an electron-withdrawing group could be anodically monofluorinated in satisfactory yields for the first time when etheral solvents were used as an electrolytic ...