Regioselectivity of hydride transfer to and between NAD+ analogs

RMG Roberts, D Ostovic…

文献索引：Roberts, R. M. G.; Ostovic, D.; Kreevoy, M. M. Journal of Organic Chemistry, 1983 , vol. 48, # 12 p. 2053 - 2056

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被引用次数: 42

摘要

Results Reduction Products. Reduction of quinolinium ions (1) with NaBH, in water or a water-methanol mixture generally gives mixtures of substituted 1, 2-(2) and 1, 4- dihydroquinolines (3) in which the 1, 2-isomers predominate. The relative amounts of the isomers present in the initial product mixture were determined from its' H NMR spectrum, as described in the Experimental Section. Sometimes no l, 4-isomer at all could be detected. ...