Bulletin of the Chemical Society of Japan

The Reactions of Group V Metal Amide with Sulfur Dioxide

F Ando, J Koketsu, Y Ishii

文献索引：Ando,F. et al. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 1481 - 1483

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被引用次数: 6

摘要

Tris (dialkylamino)-arsines (I),-stibines (II), and-bismuthines (III) react with sulfur dioxide to give the corresponding tetraalkylsulfurous diamides and the corresponding metal oxides or polymers containing the metals. The reactivity of these metal amides in view of the fastness of the initial reactions follows the order III> II> I, however, the yields decrease in the order I> II> III. Tris (dialkylamino) phosphines, on the other hand, give hexaalkylphosphoric ...