Synthetic reactions by complex catalysts. XXXVII. Novel and versatile method of carbodiimide synthesis oxidation of carbene palladium (II) complex with silver oxide
Y Ito, T Hirao, T Saegusa
文献索引:Ito,Y. et al. Journal of Organic Chemistry, 1975 , vol. 40, p. 2981 - 2982
For several years, there has been much interest in metalcarbene complexes.'However, most studies are concerned with the isolation and characterization of stable metal-carbene complexes' and with the mechanism of reactions involving transient metal-carbene intermediates. 2 Studies of the synthetic applications of metal-carbene complexes are scanty. In preceding papers, we have reported that Cu (I), Ag (I), and Au (II1) salts catalyze ...