The Journal of Organic Chemistry

Titanium tetrachloride promoted reactions of allylic trimethylsilanes and oxetane

SA Carr, WP Weber

文献索引：Carr, Steve A.; Weber, William P. Journal of Organic Chemistry, 1985 , vol. 50, # 15 p. 2782 - 2785

全文：HTML全文

被引用次数: 32

摘要

We would like to report that the titanium tetrachloride promoted reaction of allylic trimethylsilanes with oxetanes yields 5-hexen-1-ols as products (Table I). We anticipated that this reaction might be successful due to the similar strain energy of oxetanes and epoxides (25 kcal/mol) 1 as well as on the basis of our previous work on the reactions of oxetanes with dimethylsilylene,"(methy1thio) trimethylsilane, l2 and trimethylsilyl cyanide. ...