Synthesis of calix [4] resorcinarenes, containing phosphoryl fragments at the lower rim of the molecule

…, IR Knyazeva, YM Sadykova, MA Pudovik…

文献索引：Burilov; Knyazeva; Sadykova; Pudovik; Habicher; Baier; Konovalov Russian Chemical Bulletin, 2007 , vol. 56, # 6 p. 1144 - 1148

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被引用次数: 8

摘要

Abstract Reaction of resorcinol with phosphorylated acetals or ethoxyvinylphosphonic acid esters in acidic media leads to calix [4] resorcinarenes, containing dialkoxyphosphoryl fragments at the lower rim of the molecule. When the alkyl substituent in alkoxy groups at phosphorus atom is not very long, a partial hydrolysis of the initially formed products takes place to give calixarenes with alkoxyhydroxyphosphoryl fragments.