The Journal of Organic Chemistry

The Synthesis of 2-Nitrocyclohexanone and the Reaction of Acetyl Nitrate with Cyclohexene

AA Griswold, PS Starcher

文献索引：Griswold,A.A.; Starcher,P.S. Journal of Organic Chemistry, 1966 , vol. 31, p. 357 - 361

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被引用次数: 20

摘要

The synthesis of Znitrocyclohexanone was accomplished by the chromic acid oxidation of 2- nitrocyclohexanol and by the reaction of acetyl nitrate with cyclohexen-1-01 acetate. The reaction of acetyl nitrate with cyclohexene was shown to produce the previously unreported 4nitrocyclohexene in addition to the previously re-ported 2-nitrocyclohexyl acetate, 2- nitrocyclohexyl nitrate, and 3-nitrocyclohexene.