Lithium perchlorate as a reagent for synthesis of covalently bonded organic perchlorates via electrophilic additions of halogens and nitronium fluoroborate to olefins

NS Zefirov, AS Koz'min, VV Zhdankin…

文献索引：Zefirov, N.S.; Koz'min, A.S.; Zhdankin, V.V.; Nikulin, A.V.; Zyk, N.V. Journal of Organic Chemistry, 1982 , vol. 47, p. 3679 - 3684

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被引用次数: 22

摘要

The reaction of a series of olefins with chlorine and bromine in the presence of a large exma of lithium perchlorate in ether gave l,%-halo perchlorates together with the corresponding 1, 2-dihalides. Analogous reactions of N02BF, in the presence of LiC104 in methylene chloride or ethyl acetate with monoolefins gave 1, 2-nitro perchlorates. Norbornadiene reacted with a N02BF4/LiC104 system to give two isomeric nitro perchlorates of nortricyclenic structure. ...