Journal of the American Chemical Society

Photochemical transformations. XIII. Photorearrangements of 3-phenylcycloheptene and some phenylnorcaranes

SJ Cristol, CS Ilenda

文献索引：Cristol,S.J.; Ilenda,C.S. Journal of the American Chemical Society, 1975 , vol. 97, p. 5862 - 5867

被引用次数: 6

摘要

Abstract: While irradiation of 3-phenylcycloheptene (12) in cyclohexane or acetonitrile did not lead to isomeric products, that in benzene led to a mixture of 2- phenylmethylenecyclohexane (15) and cis-and trans-2-phenylnorcarane (16 and 17) rather than to the anticipated di-*-methane product, endo-(or exo-)-7-phenylnorcarane. endo-7- Phenylnorcarane (13) iso-merized to the exo isomer (14) when irradiated in ketonic ...

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