Chemistry Letters

Palladium-Catalyzed Regio-and Stereoselective Reduction of Allylic Compounds with LiHBEt 3. Application to the Synthesis of Co-enzyme Q 10

…, H Kinoshita, K Inomata, H Kotake, H Takagaki…

文献索引：Mohri, Mitsunobu; Kinoshita, Hideki; Inomata, Katsuhiko; Kotake, Hiroshi; Takagaki, Hidetsugu; Yamazaki, Keiji Chemistry Letters, 1986 , p. 1177 - 1180

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被引用次数: 45

摘要

Regio-and stereoselective desulfonylation of allylic sulfones with LiHBEt 3 in the presence of a catalytic amount of [PdCl 2 (dppp)] was successfully applied to the synthesis of co- enzyme Q 10. It was found that this reduction system was applicable to a wide variety of allylic functional groups.