A new route to thio-and selenosulfonates from disulfides and diselenides. Application to the synthesis of new thio-and selenoesters of triflic acid

…, BR Langlois, S Large, D Anker, N Roidot…

文献索引：Billard, Thierry; Langlois, Bernard R.; Large, Sylvie; Anker, Daniel; Roidot, Nathalie; Roure, Philippe Journal of Organic Chemistry, 1996 , vol. 61, # 21 p. 7545 - 7550

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被引用次数: 42

摘要

Alkyl and aryl trifluoromethanethiosulfonates1 (or selenosulfonates) were prepared in one step either from alkyl and aryl sulfenyl (or selenenyl) chlorides and sodium trifluoromethanesulfinate (3) or, more generally, from disulfides (or diselenides), 3, and bromine. The second method involved trifluoromethanesulfonyl bromide as key intermediate. Benzenethiosulfonates were obtained in a similar way from disulfides, ...