Electron and oxygen transfer in polyoxometalate, H5PV2Mo10O40, Catalyzed oxidation of aromatic and alkyl aromatic compounds: evidence for aerobic Mars-van …

…, L Weiner, Y Wang, R Neumann

文献索引：Khenkin; Weiner; Wang; Neumann Journal of the American Chemical Society, 2001 , vol. 123, # 35 p. 8531 - 8542

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被引用次数: 134

摘要

The mechanism of aerobic oxidation of aromatic and alkyl aromatic compounds using anthracene and xanthene, respectively, as a model compound was investigated using a phosphovanadomolybdate polyoxometalate, H5PV2Mo10O40, as catalyst under mild, liquid- phase conditions. The polyoxometalate is a soluble analogue of insoluble mixed-metal oxides often used for high-temperature gas-phase heterogeneous oxidation which ...