The Journal of chemical physics

Spectroscopy of jet??cooled metal–monocyclopentadienyl complexes: Laser excitation spectra of calcium and cadmium cyclopentadienides

AM Ellis, ESJ Robles, TA Miller

文献索引：Ellis, Andrew M.; Robles, Eric S. J.; Miller, Terry A. Journal of Chemical Physics, 1991 , vol. 94, # 3 p. 1752 - 1758

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被引用次数: 31

摘要

A laser vaporization/photolysis technique for obtaining spectra of jet??cooled organometallic molecules is reported. It makes use of an excimer laser which vaporizes a metal sample and simultaneously photolyzes an organic precursor passing over the surface of the metal. The metal atoms and organic fragments then react to yield the organometallic species. In principle, this approach could be used to prepare a wide variety of gas??phase compounds ...