Tetrahedron letters

Preparation of trifluoromethyl-substituted alcohols from allylsilanes and trifluoroacetic anhydride

H Pellissier, S Wilmouth, M Santelli

文献索引：Pellissier, Helene; Wilmouth, Serge; Santelli, Maurice Tetrahedron Letters, 1996 , vol. 37, # 29 p. 5107 - 5110

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被引用次数: 22

摘要

The titanium tetrachloride-mediated addition of allyltrimethylsilane or 1, 8-bis (trimethylsilyl)- 2, 6-octadiene and trifluoroacetic anhydride led to trifluoromethyl-diallylcarbinol or (dl)-1- trifluoromethyl-2, 5-divinylcyclopentanol, respectively, in fair yields; this latter was further converted into several 1-trifluoromethyl-2-vinylcyclopentane derivatives.