The reaction of 5-benzylidene-2, 3, 4, 5-tetrahydropyridine with some nucleophiles

Y Nomura, T Bando, Y Takeuchi…

文献索引：Nomura, Yujiro; Bando, Takashi; Takeuchi, Yoshito; Tomoda, Shuji Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 5 p. 1271 - 1275

全文：HTML全文

被引用次数: 4

摘要

The reaction 5-benzylidene-2, 3, 4, 5-tetrahydropyridine (1) with nucleophilic reagents, such as sodium tetrahydroborate, lithium tetrahydridoaluminate, organometallic reagents, pyrrole, or ethyl propiolate, has been studied. The reaction of 1 with sodium tetrahydroborate, lithium tetrahydridoaluminate, phenylmagnesium bromide, butyllithium gave exclusively respective 1, 2-adducts. The reaction with pyrrole gave a tricyclic 1: 1 adduct while 1 formed a 1: 2 ...