Rate coefficient for the reaction of hydroxymethyl radicals with chlorine and infrared spectra of chloromethanol and dichloromethanol

…, TJ Wallington, MD Hurley, WF Schneider

文献索引：Tyndall, Geoffrey S.; Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F. Journal of Physical Chemistry, 1993 , vol. 97, # 8 p. 1576 - 1582

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被引用次数: 43

摘要

Results Chloromethanol and dichloromethanol were prepared by the UV irradiation of CHSOH-CI~ mixtures in N2 diluent. Figure lA, B shows spectra acquired at Ford before and after a 2-s irradiation of a mixture of 98 mTorr of Clz and 14.8 mTorr of methanol. The loss of methanol was 4.07 mTorr (28%). Subtraction of CH3OH features from Figure 1 B yields the product spectrum C. Product features wereokervedat 959, 1083, 1318, and 1374 cm-'. ...