Rate coefficients for the reactions of chlorine atoms with methanol and acetaldehyde

…, CS Kegley??Owen, TJ Wallington…

文献索引：Tyndall; Orlando; Kegley-Owen; Wallington; Hurley International Journal of Chemical Kinetics, 1999 , vol. 31, # 11 p. 776 - 784

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被引用次数: 52

摘要

Abstract Rate coefficients have been measured for the reactions of Cl atoms with methanol (k 1) and acetaldehyde (k 2) using both absolute (laser photolysis with resonance fluorescence) and relative rate methods at 295±2 K. The measured rate coefficients were (units of 10− 11 cm 3 molecule− 1 s− 1): absolute method, k 1=(5.1±0.4), k 2=(7.3±0.7); relative method k 1=(5.6±0.6), k 2=(8.4±1.0). Based on a critical evaluation of the literature ...