An aluminum ate base: Its design, structure, function, and reaction mechanism

H Naka, M Uchiyama, Y Matsumoto…

文献索引：Nakamura, Shinji; Uchiyama, Masanobu Journal of the American Chemical Society, 2007 , vol. 129, # 1 p. 28 - 29

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被引用次数: 143

摘要

An aluminum ate base, i-Bu3Al (TMP) Li, has been designed and developed for regio-and chemoselective direct generation of functionalized aromatic aluminum compounds. Direct alumination followed by electrophilic trapping with I2, Cu/Pd-catalyzed CC bond formation, or direct oxidation with molecular O2 proved to be a powerful tool for the preparation of 1, 2- or 1, 2, 3-multisubstituted aromatic compounds. This deprotonative alumination using i- ...