Canadian Journal of Chemistry

Fragmentation of alkoxide ions following collisional activation. An energy-resolved study

RS Mercer, AG Harrison

文献索引：Mercer, Roger S.; Harrison, Alex G. Canadian Journal of Chemistry, 1988 , vol. 66, p. 2947 - 2953

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被引用次数: 21

摘要

The collisionally activated dissociation reactions of the C2 to C5 alkoxide ions have been studied for collisons occurring at 8 keV kinetic energy and also over the range 5 to 100 eV kinetic energy. The alkoxide ions fragment by 1, 2-elimination of H2 and/or an alkane. Thus, primary alkoxide ions fragment by elimination of H2 only, secondary alkoxide ions show elimination of H2 and alkane molecules, while tertiary alkoxide ions show elimination of ...