Journal of the American Chemical Society

Gas-phase reactions of the methyl anion

ST Graul, RR Squires

文献索引：Graul, Susan T.; Squires, Robert R. Journal of the American Chemical Society, 1989 , vol. 111, # 3 p. 892 - 899

全文：HTML全文

被引用次数: 40

摘要

Abstract: We report the first direct observations of ion/molecule reactions of the methyl anion CH3-in the gas phase. Methyl anions are generated by means of collision-induced dissociation (CID) of CH3C02-or CH3CH20-in a flowing afterglow-triple quadrupole instrument. Ion/molecule reactions of CH3-can be observed when CID is effected in the presence of reactive gases under appropriate conditions of collision energy and reactant ...