Preparation and rearrangement of some conjugated phenylsulphinylacetate derivatives

…, AA Jaxa-Chamiec, PG Sammes

文献索引：Cass, Quezia B.; Jaxa-Chamiec, Albert A.; Sammes, Peter G. Journal of the Chemical Society, Chemical Communications, 1981 , # 24 p. 1248 - 1250

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被引用次数: 6

摘要

The direct condensation of saturated or un-saturated aldehydes with methyl phenylsulphinylacetate can be effected with the products undergoing base catalysed rearrangements those from saturated aldehydes yielding γ-hydroxy-αβ-unsaturated esters, whilst croton-aldehyde gives rise to methyl 6-phenylsulphinylhexa-2, 4-dienoate.