Alkylation and acylation of some activated aromatic substrates by organosilicon compounds

GA Artamkina, SV Kovalenko, IP Beletskaya…

文献索引：Artamkina, G. A.; Kovalenko, S. V.; Beletskaya, I. P.; Reutov, O. A. Journal of Organometallic Chemistry, 1987 , vol. 329, # 2 p. 139 - 150

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被引用次数: 10

摘要

Abstract A method of alkylation and acylation of trinitrobenzene employing the oxidation of anionic σ-complexes generated from organosilicon reagents in the presence of KF/18-crown- 6 ether is described. The method enables the introduction of alkyl and acyl substituents (R= Full-size image (< 1 K)