Chemistry Letters

Boron-Metal Exchange Reaction of Silylboranes with Organometallic Reagents: A New Route to Arylsilyl Anions.

A Kawachi, T Minamimoto, K Tamao

文献索引：Kawachi, Atsushi; Minamimoto, Takashi; Tamao, Kohei Chemistry Letters, 2001 , # 12 p. 1216 - 1217

被引用次数: 17

摘要

The boron–metal exchange reaction of (arylsilyl) boranes with alkyllithiums, potassium tert- butoxide, and methylmagnesium bromide affords the corresponding silyllithium, silylpotassium, and silylmagnesium compounds, respectively. Especially, the boron–lithium exchange reaction occurs even in hydrocarbon solvents such as toluene and hexane as well as in THF.

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