Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction

…, H Kondo, J Sato, Y Yamanoi, H Nishihara

文献索引：Lesbani, Aldes; Kondo, Hitoshi; Sato, Jun-Ichi; Yamanoi, Yoshinori; Nishihara, Hiroshi Chemical Communications, 2010 , vol. 46, # 41 p. 7784 - 7786

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被引用次数: 20

摘要

Hypersilyl substituted arenes ((Me 3 Si) 3 Si–Ar) have emerged as an important class of organosilanes due to their unique optical and electronic properties. 1 These properties originate from the delocalized σ-bonds in the catenated silicon framework and are strongly influenced by functional substituents attached to the silicon atoms. Because these compounds have shown effective σ–π conjugation between the oligosilane σ-orbitals and the π-orbitals, oligosilanes may act as good ...