Conversion of nitro paraffins into aldehydes and ketones

…, AS Erickson, WJ Kelly, B Henggeler

文献索引：Kornblum, Nathan; Erickson, Allen S.; Kelly, William J.; Henggeler, Barbara Journal of Organic Chemistry, 1982 , vol. 47, # 23 p. 4534 - 4538

全文：HTML全文

被引用次数: 52

摘要

Conclusion The MNDO reaction paths reported agree remarkably well with the observed and best theoretical estimates of the relative energies of the stable species and transition states for stepwise thermolyses of 1-3. Concerted paths are much higher in energy. The preferred reaction sequence for most trans-azoalkanes should involve the cis transition state.