Conversion of nitro paraffins into aldehydes and ketones

…, AS Erickson, WJ Kelly, B Henggeler

Index: Kornblum, Nathan; Erickson, Allen S.; Kelly, William J.; Henggeler, Barbara Journal of Organic Chemistry, 1982 , vol. 47, # 23 p. 4534 - 4538

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Citation Number: 52

Abstract

Conclusion The MNDO reaction paths reported agree remarkably well with the observed and best theoretical estimates of the relative energies of the stable species and transition states for stepwise thermolyses of 1-3. Concerted paths are much higher in energy. The preferred reaction sequence for most trans-azoalkanes should involve the cis transition state.