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Cyclopropane Derivatives. I. Studies of the Photochemical and Thermal Chlorination of Cyclopropane

JD Roberts, PH Dirstine

文献索引:Roberts; Dirstine Journal of the American Chemical Society, 1945 , vol. 67, p. 1281,1282

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被引用次数: 31

摘要

Summary 1. A simple isothermal calorimeter is described which is suitable for determination of heats of polymerization. Its operation using methyl methacrylate is illustrated. 2. The heat of polymerization of methyl methacrylate was found to be 13.0* 0.2 kcal./mole. This value did not change with temperature or catalyst concentration within the limits investigated.