Journal of the American Chemical Society

The Effect of Ring Size on Diacyl Peroxide Decompositions1, 2

H Hart, DP Wyman

文献索引：Hart; Wyman Journal of the American Chemical Society, 1959 , vol. 81, p. 4891,4896

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被引用次数: 57

摘要

Cycloalkaneformyl (13-7) and cycloalkaneacetyl (II& 6) peroxides were prepared and their products and rates of decomposition in carbon tetrachloride studied. A large variation in rate (102) was observed for type I peroxides, IS being remarkably slow. But the cycle-propyl radical, once formed, reacted with the solvent (giving cyclopropyl chloride) rather than isomerize to the more stable allyl radical. In anhydrous carbon tetrachloride containing ...