Bicyclo [1.1. 0] butane Chemistry. I. The Synthesis and Reactions of 3-Methylbicyclo [1.1. 0] butanecarbonitriles

EP Blanchard Jr, A Cairncross

文献索引：Blanchard,E.P.; Cairncross,A. Journal of the American Chemical Society, 1966 , vol. 88, p. 487 - 495

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被引用次数: 45

摘要

Abstract: The hydrohalogenation-dehydrohalogenation of 3- methylenecyclobutanecarbonitriles provides a facile, high-yield synthesis of 3-methylbicyclo [l. lO] butanecarbonitriles. The latter react with a broad spectrum of reagents including acids, electron-deficient multiple bonds, nucleophiles, free radicals, and halogens to give cyclobutanes and cyclobutenes. The bicyclobutane ring system is thermally labile leading ...