Sur les organometalliques issus de thioamides: I. Reactivite avec les aldehydes et cetones; stereochimie de la condensation avec la t-butyl-4 cyclohexanone et le …
Abstract Organometallic compounds derived from thioamides RCH 2 CSN (R 3) 2 condense normally with aldehydes and saturated ketones. Condensation with 4-t-butyl-cyclohexanone leads predominantly to equatorial attack by the organometallic compound. These results suggest that the organometallic structure as RCH C (SM) N (R 3) 2.
