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Douglas fir tussock moth pheromone: Identification of a diene analog of the principal attractant and synthesis of stereochemically defined 1, 6-, 2, 6-, and 3, 6- …

LM Smith, RG Smith, TM Loehr…

文献索引:Smith,L.M. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 2361 - 2366

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被引用次数: 23

摘要

A diene analogue of the principal Douglas fir tussock moth sex pheromone (Z)-6- heneicosen-ll-one has been isolated and identified as a 1, 6-heneicosadien-ll-one using mass spectrometry, microozonolysis, and gas chromatography. Five geometric and positional heneicosadien-11-one isomers were synthesized for chromatographic and spectroscopic comparison and for biological testing. Unambiguous structural assignments ...