Heterocycles

Total synthesis of (′)-xyloketal D and model studies towards the total synthesis of (-)-xyloketal A

JD Pettigrew, JA Bexrud, RP Freeman, PD Wilson

文献索引：Pettigrew, Jeremy D.; Bexrud, Jason A.; Freeman, Rebecca P.; Wilson, Peter D. Heterocycles, 2004 , vol. 62, p. 445 - 452

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被引用次数: 36

摘要

Résumé/Abstract A stereoselective total synthesis of (′)-xyloketal D (′-2) has been achieved using a cycloaddition reaction of an ortho-quinone methide and a dihydrofuran as a key step. Preliminary model studies towards the total synthesis of xyloketal A (1) are also reported.