Platinum nanoparticles supported on zirconia mediated synthesis of N-acyl and N-(tert-butoxycarbonyl) amines from nitroarenes and azides

…, R Chakravarti, B Sreedhar, F Figueras…

文献索引：Kantam, M. Lakshmi; Reddy, R. Sudarshan; Srinivas; Chakravarti; Sreedhar; Figueras; Venkat Reddy, Ch. Journal of Molecular Catalysis A: Chemical, 2012 , vol. 355, p. 96 - 101

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被引用次数: 11

摘要

A convenient and useful protocol has been designed for the synthesis of N-aryl acetamides from the corresponding nitro compounds via a reductive N-acylation process using bi- functional, recyclable heterogeneous platinum nanoparticles supported on zirconia [Pt (0)/ZrO2] catalyst, employing molecular hydrogen as the environmentally benign reductant and the corresponding anhydrides as acylating agents. N-Boc protected amines were also ...